Each episode of this series include multiple segments: The first and last were "Laff-A-Lympics" segments, the other ones were "Captain Caveman and the Teen Angels", "Scooby-Doo" and "Dynomutt" segments. The "Laff-A-Lympics" segments feature 45 Hanna-Barbera cartoon characters (classic and otherwise) competing for gold medals in wacky events. Events include racing on ostriches, camels, kangaroos, rickshaws and unicycles, as well as scavenging for creatures like the Abominable Snowman, vampires, and the Loch Ness Monster.
"On a charter boat, Captain Caveman and the Teen Angels are chatting with a friend whose father is being honored for his role in a play when suddenly the lights go out and a necklace is stolen."
"As Dynomutt escapes, Blue Falcon becomes Blue Blob. Dog Wonder races his blue buddy to The Falcon's Lair, where he sculpts him back to normal and spritzes him with The Falcon Instant Hardening Spray, and corner The Glob and his minions just as they nab the true Baltese Falcon. They capture Norbert Prindle in a huge goblet, and turn the crooks in and return the Falcon to the Crowne Art Gallery. Later, in the Falcon's Lair, D.W. tries to sculpt a \"\"Bluetese Falcon\"\", using B.F. for a model, but his creation shatters to pieces before he gets to profit big from it."
"The Daring Duo are on the trail of Madame Ape Face who has swiped the face of Sophia Florenzi and plans tosteal all of the beautiful faces of the starlets of Big City. They catch up with The Madame at GaGa Galore's costume party but her face is stolen. Chasing Ape Face , Blue Falcon and Dog Wonder find themselves headed down a conveyor belt into a cold cream machine!"
"The gang spends a stormy night at Hatfield's cabin, only to see a witch transform their host into a frog. Searching for a solution, they encounter a zombie and a witch's cave."
"Saved by The Falcon Fan Snapper, The Daring Duo rush to the aid of the most probable victims. When Fifi Foray wins a beauty contest, Dog Wonder disguises himself as Fifi, and an ensuing scuffle with Madame Ape Face results in D.W.'s face stolen. (Dynoape, Ape Wonder?! It'll never be the same!) Using The Dyno-Radar Hand Detector, the heroes find The Madame's lair and Dog Wonder's face is restored. They catch Ape Face in the act of pilfering Sarah Showerfaucet's face at her apartment. Blue Falcon captures The Madame just as she tosses Sarah's face out the window, but Dog Wonder manages to catch it before it shatters on the concrete below."
"Lurking in Big City is The Shadowman, who mysteriously knows all of the plans of The Crime Commission. The Daring Duo are called in when the 700-karat Shmope Diamond is swiped. As they respoind, they spot a shadow sneaking off with plates for new $20 bills stolen from an armored car. The Shadowman later manages to kill two birds with one stone by making off with a secret gold shipment and framing Mayor Gaunt (who is captured in The Dyno Bad Guy Box) all in one shot."
"A huge sea monster disrupts the kids' beach party, but when they take refuge in an old house they run into a ghostly sea captain whose spirit has been stolen by the monster."
"With their friend, a prince of a small country, Captain Caveman and the Teen Angels go skiing. When the scepter is stolen by a Snowwolfman, they investigate."
"Captain Caveman and the Teen Angels are assisting Dee Dee's uncle, Frank Skyes, with a fur delivery. When the furs disappear, it is up to them to find out what happened."
"In Wyoming, rumors of a horse that is possessed by a demon are rampant. And they seem to be true. Captain Caveman and the Teen Angels have arrived to investigate. Just as they are investigating, a bank robbery occurs."
"Captain Caveman and the Teen Angels go to a research facility after they spot an alien spacecraft landing there. They discover that an alien robot supposedly stole a top secret energy source."
"Captain Caveman and the Teen Angels got to Farthington Mansion with Taffy's Aunt Gladys to see a magic show. When some jewels are stolen, Captain Caveman and the Teen Angels investigate."
"In Oregon, when the star athlete of a sports team is kidnapped, Captain Caveman and the Teen Angels investigate. Very soon, they have found Juice Brenner. Or have they? He is acting strangely."
"The gang goes to visit their friend Antonio in Venice, Italy, and find that he's haunted by the ghost of an ancestor, the Ghostly Gondoleer, who seeks to steal the ancient necklace\/family heirloom Antonio wears!"
"While at a Wild West show in Dodge City, some money disappears from a saddle bag that two bandits who were really actors pretended to steal from a stagecoach that Captain Caveman and the Teen Angels were riding."
"While touring England, the gang comes upon tennis star Jimmy Pelton, who's been cursed by the Warlock Anthos and told if he plays at Wimbledon, he's doomed!"
"On a fishing trip, the gang ends up in Canada at the newly deserted village of Bottomless Lake. Turns out the beast has scared everyone away, which only leaves Scooby, and the gang, to fritter away."
"Captain Caveman and the Teen Angels decide to investigate when a missile launch they have been watching in the Grand Canyon, where they had previously competed in the Laff-A-Lympics, goes awry."